Photo/Electrochemical‐Mediated C(sp<superscript>3</superscript>)−H Bond Functionalization of (Thio)Ethers.
In: European Journal of Organic Chemistry, Jg. 27 (2024-05-03), Heft 17, S. 1-14
Online
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Zugriff:
Molecules containing ether skeletons are widely present in drugs, natural products, functional materials, and life science. Direct C(sp3)−H bond ether functionalization is considered a powerful strategy for the construction of novel ether derivatives. Photo‐/electro‐chemical technology is a relatively green and sustainable synthesis method, which opens up a broad application prospect in the field of direct functionalization of C(sp3)−H bonds. In recent years, photo‐/electro‐mediated C(sp3)−H bond alkylation, arylation, alkynylation, esterification, mercaptoylation, sulfidation, and amination of ethers have been extensively studied. In this review, the research progress of photo‐/electro‐mediated C(sp3)−H bond functionalization of ether compounds from 2014 to 2023 is systematically reviewed, and the scope, limitations, and mechanisms for some reactions are discussed. [ABSTRACT FROM AUTHOR]
| Titel: |
Photo/Electrochemical‐Mediated C(sp<superscript>3</superscript>)−H Bond Functionalization of (Thio)Ethers.
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| Autor/in / Beteiligte Person: | Sun, Lianglong ; Zhao, Dongyang ; Sun, Kai ; Liu, Fei ; Yang, Shubing ; Chen, Si ; Wang, Xin |
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| Zeitschrift: | European Journal of Organic Chemistry, Jg. 27 (2024-05-03), Heft 17, S. 1-14 |
| Veröffentlichung: | 2024 |
| Medientyp: | academicJournal |
| ISSN: | 1434-193X (print) |
| DOI: | 10.1002/ejoc.202400057 |
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